翻訳と辞書 |
Crabtree's catalyst : ウィキペディア英語版 | Crabtree's catalyst
Crabtree's catalyst is an organoiridium compound with the formula C8H12IrP(C6H11)3C5H5N]PF6. It is a homogeneous catalyst for hydrogenation and hydrogen-transfer reactions, developed by Robert H. Crabtree. This air stable orange solid is available commercially. ==Structure and synthesis== The complex has a square planar molecular geometry, as expected for a d8 complex. It is prepared from cyclooctadiene iridium chloride dimer.〔Crabtree, R. H., Morris, G. E. (1977). "Some diolefin complexes of Iridium(I) and a ''trans''-Influence Series for the Complexes ()", J. Organomet. Chem, 135(3), 395-403, 〕
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Crabtree's catalyst」の詳細全文を読む
スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース |
Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.
|
|